Bioethanol Production From Coconut Coir Using Ozonolysis-Hydrolysis-Fermentation-Distillation-Silica Gel Adsorption Method
Abstract
The utilization of coconut coir as a feedstock for bioethanol production offers an innovative approach to valorize agricultural residues in the South Sumatra region. Given the high lignin content of coconut coir, a lignin removal pretreatment was necessary to enhance the accessibility of cellulose for hydrolysis. This study investigated the impact of ozonolysis duration on lignin and cellulose content, efficacy of silica gel adsorption. The experimental design involved ozonolysis, hydrolysis, fermentation, distillation, and silica gel adsorption. Results revealed that 25 minutes of delignification significantly reduced lignin content by 8,3% while increasing cellulose content by 3,1%. Optimal ozonolysis conditions, coupled with pH stabilization at 4.5 using NaOH, led to enhanced 500 mL bioethanol volume after 7 days fermentation. Application of 10 grams white silica gel for 60 minutes showed an ethanol content of 97% from GC-MS analysis.
Full Text:
FULL TEXT PDFReferences
N. E. Alsari and Amaria, “Pemanfaatan Zeolit Alam Aktif Sebagai Adsorben Bioetanol Ampas Tebu,” UNESA Journal of Chemistry Vol. 12, No. 2. 2023.
S.A. Jambo, R. Abdulla, S.H.M. Azhar, H. Marbawi, J.A. Gansau, and P. Ravindra, “A review on third generation bioethanol feedstock,” Renew. Sustain. Energy Rev. 65, 756–769. 2016.
Sugiartono, Wagiono, D. Afdal, and R. Wahyudi, “The Utilization of Young Coconut Waste Bioethanol and its Effect on four-stroke Engine Emissions,” Journal of Automotive Engineering and Vocation Education. Vol. 01, No. 01. 2020.
Disbun Sumsel, “Dinas Perkebunan (Disbun) Provinsi Sumatera Selatan catat jumlah produksi kelapa 61.724 ton,” disbun.sumselprov.go.id. 2022.
L. Mishra and G. Basu, “Coconut fibre : its structure, properties and applications,” Handbook of Natural Fibers. 2020.
I.B. Martinez, N. Guzman, E. Pena, T. Vazquez, R.C. Camacho, J. Folch, J.A.H. Salazar, and J. Aburto, “Ozonolysis of alkaline lignin and sugarcane bagasse: Structural changes and their effect on saccharification,” Biomass and Bioenergy, 94, 167. 2016.
E.M. Ben, O. R. Manisova, and V.V. Lunin, “Effect of Moisture Content on the Interaction between Lignocellulosic Materials and Ozone,” Russian Journal of Physical Chemistry, 91 (7), 1190. 2017.
S.K. Tripathi, N.K. Bhardwaj, and H.R. Ghatak, “Determination of main parameters affecting Ozone bleaching of wheat straw pulp using plackett – burman design determination of main parameters affecting ozone bleaching of wheat straw,” Ozone Science English, 40 (2), 1. 2017.
R. Travaini, J. Martin-Juarez , A. Lorenzohernando, and S. Bolado-Rodriguez, “Ozonolysis: An advantageous pretreatment for lignocellulosic biomass revisited,” Bioresource Technology, 199, 2. 2015.
A. Azimi, M.J. Javan, S. Ahmadi, M, Rouhani, and Z. Mirjafary, “Unraveling the Ozonolysis Mechanism of Terpinolene: Insights from DFT Studies,” International Journal of New Chemistry, 11 (4), 443-456. 2024.
D.D. Anggoro, I.K. Dewi, L. Buchori, and A. Prasetyaningrum, “Parametric Optimization Of Oil Palm Mesocarp Fiber Valorization With Hybrid Ozonationultrasonic Pretreatment Method,” Iium Engineering Journal, Vol. 24, No. 2. 2023.
A.M. Jannah, M. Faizal, Novia., and H. Widjajanti, “The Effects of Ozonolysis on Oil Palm Fruit Mesocarp Delignification,” Journal of Ecological Engineering, 25(7), 305–316. 2024.
A.P. Siswanto, M.E. Yulianto, D. Handayani, E.F. Sapatra, I. Yuniarti, and R.A.S. Imamsyah, “Morphology characterization of lignocellulosic materials in ozone based degradation,” IOP Conf. Series: Materials Science and Engineering 845 012048. 2020.
O. M. Perrone, M.M.D.S. Moretti, S.E. Bordignon, J.D.S. Pereira, R.D. Silva, E. Gomes, and M. Boscolo, “Improving cellulosic ethanol
RT:0.00 - 4.090.00.51.01.52.02.53.03.54.0Time (min)0102030405060708090100Relative Abundance1.151.031.721.911.393.824.002.942.123.661.543.502.263.352.442.643.092.800.120.680.310.510.83NL:4.19E8TIC MS A161_240910140323
Vol. 9 No.2, 117-123 http://dx.doi.org/10.22135/sje.2024.9.2,117-123 123
production using ozonolysis and acid as a
sugarcane biomass pretreatment in mild conditions,” Bioresource Technology Reports 13100628. 2021.
W.D. Harahap, “Optimasi Proses Ozonolisis dengan Terkodop C dan Nuntuk Degradasi Diazinon,” Jurnal Kolaborasi Sains dan Ilmu Terapan Vol. 2, No. 2, | Page 43-45 | DOI :ISSN 2964- 5581.June, 2024.
N.B. Wardani, M. Susanti, Y. Maryanty, and E. Widiarto, “Hidrolisis Raw Sugar Sebagai Bahan Baku Pembuatan Mono Natrium Glutamat Dengan Variasi pH, Suhu, dan Konsentrasi,” Distilat Jurnal Teknologi Separasi, Vol. 7, No. 1. 2021.
S.A. Aksari, L.R. Alvita, F.F. Silmi, A.S. Rezki, and W. Hanifah, “Perbandingan Konsentrasi Asam Pekat (H2SO4) Dalam Proses Hidrolisis Terhadap Kadar Gula Pereduksi Kulit Kakao Sebagai Substrat Dalam Pembuatan Bioetanol,” Journal Applied of Science and Chemical Engineering Vol. 2, No. 1. Aug. 2024.
L. Marlina and W.N. Hainun, “Pembuatan Bioetanol dari Air Kelapa Melalui Fermentasi dan Destilasi-Dehidrasi Dengan Zeolit,” TEDC Vol. 14 No.3, Sept. 2020.
T.N. Villarul, Chairul, and S.R. Yenti, “Pemurnian Bioetanol Hasil Fermentasi Nirah Nipah Menggunakan Proses Destilasi Adsorpsi Menggunakan Adsorben CaO,” Jom FTEKNIK, vol. 4, no. 2. 2017.
B. Susilo, S.H. Sumarlan, and D.F. Nurirenia, “Pemurnian Bioetanol Menggunakan Proses
Distilasi
dan Adsorpsi Dengan Penambahan Asam Sulfat (H2SO4) Pada Aktivasi Zeolit Alam Sebagai Adsorben,” Jurnal Keteknikan Pertanian Tropis dan Biosistem Vol. 5No. 1, Feb 19-26.2017.
D. P. Sari and S. Tjahjani, “Pemanfaatan Kulit Durian (Durio zibethinus) Sebagai Bahan Baku Pembuatan Bioetanol Menggunakan Aspergillus niger dan Saccharomyces cerevisiae,” Prosiding Seminar Nasional Kimia. Surabaya . 22 Sept 2018.
A. Latara, S. Botutihe, and Mustofa, “Destilasi Bioetanol dari Nira Arendengan Variasi Waktu Pengadukan pada Proses Fermentasi,” Jurnal Teknologi Pertanian Gorontalo (JTPG), Vol. 5, No. 2. 2020.
A. Setiawan, A. Fatoni, and T.A. Ramadani, “Pemurnian Bioetanol Menggunakan Adsorben Silika Gel Dari Limbah Botol Kaca Di Industri Kecap,” Jurnal Pengendalian Pencemaran Lingkungan. Vol.4 No.2. 2022.
K.N. Svara1 , B.A. Harsojuwono, and I.B.W. Gunam, “Influence of adsorbent-arak ratio and distillation period in bioethanol purification process using Balinese liquor as a raw material,” Journal of Applied Horticulture, 22(3): 42-45.2021.
Megawati, “The Influence of White and Blue Silica Gels as Adsorbents in Adsorptive-Distillation of Ethanol-Water Mixture,” International Conference on Engineering, Science and Nanotechnology (ICESNANO 2016) AIP Conf. Proc. 1788, 030114-1–030114-6; 2016.
DOI: http://dx.doi.org/10.22135/sje.2024.9.2.117-123
Refbacks
- There are currently no refbacks.
Copyright (c) 2024 Sriwijaya Journal of Environment
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.